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GCSE Chemistry 2


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Elements in Group 1 of the periodic table, including lithium, sodium, potassium, rubidium, caesium, and francium.

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Alkali Metals

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What role does shielding play in alkali metal reactivity?
Shielding by inner electron shells reduces the attraction between the outer electron and the nucleus in alkali metals, making the outer electron more easily lost and contributing to increased reactivity down the group.
Name the 6 alkali metals in order of increasing reactivity
Lithium Sodium Potassium Rubidium Caesium Francium
Which group do alkali metals belong to in the periodic table?
Alkali metals belong to Group 1 in the periodic table.
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Name the 4 characteristics of the alkali metals
Low densities Soft enough to cut through with a knife Relatively low melting points (e.g., sodium: 98°C, potassium: 63°C) Highly reactive
What is a common physical property of alkali metals?
Alkali metals have low densities and are soft enough to be cut with a knife.
Explain why alkali metals are highly reactive
Have 1 electron in outer shell Easily form positive ions by losing this electron
Compare the melting point of sodium with that of iron.
Sodium has a melting point of 98°C, while iron has a much higher melting point of 1538°C.
Why are alkali metals highly reactive?
Alkali metals are highly reactive because they have just 1 electron in their outer shell, making it easy for them to lose this electron and form a positive ion.
Name 4 Alkali Metal Properties.
Low densities Softness Low melting points High reactivity due to having only one electron in their outer shell
Why does the reactivity of alkali metals increase down the group?
The reactivity increases because the number of electron shells in each atom increases. As the outer electron moves further from the nucleus and becomes more shielded by inner electron shells, its attraction to the nucleus decreases, making it more easily lost.
How does the distance from the nucleus affect reactivity in alkali metals?
As the number of electron shells increases, the outer electron in alkali metals moves further from the nucleus, reducing its attraction to the nucleus and making it more easily lost, leading to increased reactivity.
What role does shielding play in alkali metal reactivity?
Shielding by inner electron shells reduces the attraction between the outer electron and the nucleus in alkali metals, making the outer electron more easily lost and contributing to increased reactivity down the group.
What happens when alkali metals react with water?
Alkali metals react vigorously with water, producing hydrogen gas and forming metal hydroxides.
What is the result of metal hydroxides dissolving in water?
The dissolution of metal hydroxides in water produces alkaline solutions with characteristic basic properties.
How does the reactivity of alkali metals affect their reaction with water?
The more reactive an alkali metal is, the more vigorous its reaction with water. This is evident in the production of hydrogen gas and metal hydroxides.
How does potassium's reaction with water differ from lithium's?
The reaction of potassium with water is more vigorous, releasing enough energy to ignite hydrogen, (producing a lilac flame) showcasing the trend that more reactive alkali metals have more energetic reactions.
Where are Group 7 elements located on the periodic table?
Group 7 elements, also known as halogens, are found on the right side of the periodic table.
What is the molecular structure of halogens?
Halogens exist as molecules made of pairs of atoms that are covalently bonded together. An example is Cl2, where two chlorine atoms are covalently bonded.
How many electrons do halogens have in their outer shell?
Halogens have 7 electrons in their outer shell, contributing to their similar chemical reactivity.
Why do halogens all react in similar ways?
Halogens have 7 electrons in their outer shell, leading to similar reactivity patterns as they strive to achieve a stable full outer shell through chemical reactions.
What is the state of halogens at the top of Group 7 at room temperature?
Halogens at the top of Group 7 are gases at room temperature.
What factor influences the increase in melting and boiling points of halogens down the group?
The increase in melting and boiling points is influenced by the increasing relative atomic mass of halogens.
Why do larger atoms require more energy to change from a solid to a gas?
Larger atoms have stronger intermolecular forces, requiring more energy (higher temperature) to overcome these forces and transition from a solid to a gas.
How does the trend in melting and boiling points align with halogen size in Group 7?
The trend shows that as you move down Group 7, from smaller to larger halogens, the melting and boiling points increase due to stronger intermolecular forces in larger atoms.
What is the physical state and color of chlorine at room temperature?
Chlorine is a pale green gas at room temperature.
Describe the physical state and colour of bromine at room temperature.
Bromine is a red-brown liquid at room temperature.
What is the physical state and color of iodine at room temperature?
Iodine is a dark grey solid at room temperature.
How do you test for the presence of chlorine, and what is the result?
To test for chlorine (Cl2), place damp litmus paper in the test tube of gas. If chlorine is present, the litmus paper will be bleached white.
Which halogen is at the top of Group 7 and is the most reactive?
Fluorine, positioned at the top of Group 7, is the most reactive halogen.
What influences the reactivity trend of halogens down the group?
The reactivity of halogens decreases with increasing relative atomic mass.
Why does it become harder for halogens to gain an extra electron down the group?
It becomes harder down the group because the number of electron shells in each atom increases, causing the outer shell to be further away from the positive nucleus.
How does the outer shell's distance impact the reactivity of halogens?
The outer shell's increased distance makes it more challenging for halogens to gain an extra electron as it becomes more shielded from the pull of the positive nucleus, contributing to the decreasing reactivity trend down the group.
How do halogens react with other non-metals to form compounds?
Halogens react with other non-metals by sharing electrons, creating covalent bonds that allow both atoms to complete their outer shells.
What kind of structures do compounds formed by halogens and non-metals have?
Compounds formed by halogens and non-metals have simple molecular structures, consisting of just a few atoms joined together by covalent bonds.
What happens when hydrogen halides dissolve in water?
Hydrogen halides dissolve in water to create acidic solutions; for example, hydrogen chloride solution is known as hydrochloric acid: HCl(aq).
What type of compounds do halogens and metals form when they react?
Halogens and metals form ionic compounds known as metal halides when they react.
What charge does a halogen ion have after gaining an electron?
When a halogen gains an electron, it forms an ion with a charge of –1.
Describe the formation of sodium chloride (NaCl) from chlorine and sodium.
In the reaction, chlorine gains an electron to form Cl–, which is attracted to Na+ to create the ionic compound NaCl, known as sodium chloride.
What is required for a halogen displacement reaction to occur?
A more reactive halogen to (be able to) displace a less reactive halogen from an aqueous solution of its salt.
Provide an example of a displacement reaction involving chlorine, iodine, potassium AND chlorine, bromine, potassium.
Chlorine can displace iodine from a solution of potassium iodide and can displace bromine from a solution of potassium bromide.
How can you identify a displacement reaction?
Displacement reactions can be identified by observing a colour change during the reaction.
Why can chlorine displace both iodine and bromine in displacement reactions?
Chlorine is more reactive than both iodine and bromine, allowing it to displace them in displacement reactions.
What is the key characteristic of displacement reactions that makes them redox reactions?
Displacement reactions involve a transfer of electrons, making them redox reactions.
What happens to iodide ions in the chlorine-iodide reaction?
Each iodide ion (I–) loses an electron, pairing up to form iodine (I2).
How do iodide ions exhibit oxidation in the chlorine-iodide reaction?
Iodide ions (I–) lose electrons in the reaction, undergoing oxidation to form iodine.