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Index
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orgs 2
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Chapter 1
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Level 1
level: Level 1
Questions and Answers List
level questions: Level 1
Question
Answer
Oxidizes sulfur, turns dithiol into disulfide (SH-SH --> SS)
O2, FeCl3
Acid base reaction, where an acidic sulfide compound substitutes a leaving group with an SH
KSH/Ethanol
acid base reaction with sulfur. Replaces leaving group with SR'. Inversion of stereochemistry
C6H5SNa/THF or diethyl ether
oxidative cleavage, C=O created and cleaved into 2 molecules
diol + HIO4
Swern oxidation of primary alcohols, turns alcohol into aldehyde
primary alcohol + 1) (CH3)2S=O, (COCl2), CH2Cl2, heat 2) (CH3CH2)2N
Oxidation of primary and secondary alcohols to either aldehyde, ketone, or carboxylic acid
chromic acid derivative/H2SO4,H2O or PDC/PCC/CH2Cl2
Esterification. Chlorine is replaced with OR- group
primary alcohol + nitrobenzyl chloride derivative/pyridine
Fischer esterification. Alcohol in carboxylic acid is replaced with alcohol reactant OR- group
alcohol + acetic acid (Carboxylic acid with one R group) / H+ ions, benzene, heat OR H2SO4, heat
Alcohol is converted to ether. R group is doubled, oxygen in center
2 alcohols + H+, heat
Reduction methods. Reduce carboxylic acids, keynotes or aldehydes to alcohols
NaBH4 + methanol OR LiAlH4, diethyl ether, H2O OR H2, Ni, heat OR OsO4
Ring opening. MgBR is replaced by RO- group, with nucleophilic R attaching to carbon chain first
Grignard reagents + ethylene oxide (triangular oxygen) + diethyl ether and H3O+